Rethinking rectification for future energy technology
Rectification is the process of turning alternating current (AC) signals into direct current (DC), and it underpins technologies such as wireless power transfer, photodetection, terahertz sensing, and energy harvesting. To generate a one-directional current, a material normally needs a built-in directional preference for electron motion. This preference usually arises from broken inversion symmetry, meaning that the material is not identical under spatial inversion. For example, graphene has inversion symmetry, while materials with inequivalent sublattices, intrinsic electric dipoles, surfaces, or interfaces naturally break it. When inversion symmetry is broken, electrons can respond differently to opposite directions of an applied light field, allowing oscillating optical fields to generate a DC current.
In this work, the researchers show that this rule has an important exception. Even centrosymmetric bulk materials can rectify light through third-order nonlinear optical effects. Linear optical responses scale with the applied light field. Second-order responses depend on the square of the electric field and can mix frequencies or generate harmonics, but they are usually forbidden in centrosymmetric bulk materials. Third-order responses, however, are symmetry allowed and can generate DC photocurrents even when inversion symmetry is present. These currents are controlled by the shape of the Fermi surface, disorder, and the geometry of electronic bands. This means that materials once considered unsuitable for bulk optical rectification, including common metals, doped systems, and two-dimensional materials, can be engineered to convert oscillating light into DC electrical signals.

This research expands the material platform for optical rectification. Instead of relying only on noncentrosymmetric crystals, it shows that common centrosymmetric materials can also be used for light-to-DC conversion through third-order nonlinear response. This opens a route to energy-efficient photodetectors, terahertz technologies, and future energy-harvesting devices based on materials such as graphene.
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Third-order rectification in centrosymmetric metals
Sanjay Sarkar and Amit Agarwal 2026 Prog. Energy 8 025004
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