Every spring, Europe’s forests are showered with far more than rain. Wind-pollinated trees release staggering quantities of pollen into the atmosphere, and much of it eventually settles on leaves, branches and the forest floor. New research now shows that this pollen is not merely biological debris — it is a measurable, taxon-specific driver of nutrient fluxes in the water that drips through forest canopies, a flow scientists call throughfall. The findings, published in Environmental Monitoring and Assessment, provide the first continental-scale evidence directly linking pollen deposition to forest water chemistry, and they suggest that decades of forest monitoring may have been quietly misattributing a slice of nutrient input to other sources.

The study was carried out by a large international team led by Elena Gottardini of the Fondazione Edmund Mach in Italy, working within the ICP Forests programme, a pan-European network that monitors air pollution effects on forests. The researchers analysed throughfall samples collected in 2018 from 60 intensive monitoring plots — known as Level II plots — across eight countries: Belgium, Finland, France, Germany, Italy, Norway, Switzerland and the United Kingdom. The plots ranged in altitude from 14 to 1,900 metres above sea level and were dominated by six tree genera: Abies, Fagus, Larix, Picea, Pinus and Quercus. In total, 196 throughfall samples were collected between February and July, covering the early vegetative season when most European trees flower.

The innovation of the study lies in its methodology. Rather than inferring pollen inputs from nearby aerobiological samplers, the team examined the very same water samples that were being chemically analysed. A known quantity of water from each sample was filtered through a 5-micrometre cellulose nitrate mesh, and a calibrated number of 10-micrometre polystyrene-divinylbenzene microspheres — roughly 155,000 per sample — were added as a counting standard. The filters were then dissolved in acetone, centrifuged, and the resulting pellet embedded in fuchsin jelly on microscope slides. Trained analysts identified and counted pollen grains under 400-times magnification, stopping when about 1 percent of the added microspheres had been counted. From these counts, the team calculated pollen deposition rates in grains per square metre per day, correcting for filtered volume, throughfall quantity and sampling duration.

The results were striking. Fifty-three pollen taxa were identified across the samples, with woody species accounting for 98 percent of all grains. Four genera — Pinus, Picea, Fagus and Quercus — together made up 91.4 percent of the total. Pine pollen alone represented more than half of everything collected, a dominance the researchers attribute to the buoyant air sacs on pine grains, which allow them to travel enormous distances from both local and distant sources. In beech, spruce and pine stands, the pollen of the dominant genus itself prevailed, making up 49.7, 59.1 and 84.3 percent of the local pollen spectrum respectively. In oak stands, oak pollen ranked second at 26.9 percent, behind pine. Data from fir and larch stands were excluded because sampling there did not align with those genera’s flowering periods.

By combining the measured pollen curves with published flowering phenology, the team defined main pollen seasons for each genus. Beech and oak flowering spanned April and May, with beech peaking in the last week of April and oak showing a double peak at weeks 19 and 23, likely reflecting multiple oak species flowering at slightly different times across the wide latitudinal and altitudinal spread of plots. Spruce pollen peaked around weeks 19 to 20, while pine peaked at week 19 with a secondary pulse at week 22. Overall, 57 percent of the throughfall samples fell within their stand’s flowering period for at least half of their collection window, providing a robust temporal overlap between pollen deposition and water chemistry measurements.

The chemical analysis, conducted at the Research Institute for Nature and Forest laboratory in Belgium, quantified major ions including potassium, calcium, magnesium, sodium, chloride, phosphate, sulphate, nitrate, nitrite and ammonium using ion chromatography, alongside total dissolved nitrogen and non-purgeable organic carbon measured on a TOC/TN analyser. Linear mixed-effects models then tested whether pollen deposition rates could predict the flux of these compounds, with plot identity included as a random effect and autocorrelation between repeated samples explicitly modelled.

The answer was a clear yes. Every statistically significant association between pollen and throughfall chemistry was positive, meaning more pollen corresponded to more nutrients reaching the forest floor. Potassium emerged as the star player: its flux was significantly explained by pollen from all four main genera, with pollen accounting for an average of 33 percent of the variance. This makes biochemical sense, because potassium is one of the predominant ions in pollen grains, and pollen washed from flowers and crowns by rain or deposited dry is a direct source of the ion during the flowering season — an idea first proposed decades ago but never confirmed at this scale. The strongest single relationships involved oak pollen, which explained 77.8 percent of the variance in ammonium fluxes and 55 percent in total dissolved nitrogen.

Broadleaved and coniferous pollen left different chemical fingerprints. Beech and oak pollen together significantly explained fluxes of non-purgeable organic carbon, dissolved organic nitrogen, total dissolved nitrogen, ammonium and magnesium, while the combined pollen of pine and spruce was linked with every measured compound except phosphate. Intriguingly, broadleaved pollen showed a weak negative association with nitrate fluxes. The authors urge caution in interpreting this pattern, since several non-exclusive mechanisms could be at play. Laboratory experiments have shown that pollen and its associated microbiota can transform extracellular nitrate into nitrite and nitrous oxide, an effect pronounced in beech and oak but weak or absent in pine and spruce. Canopy uptake of nitrogen and coincidentally lower atmospheric deposition during broadleaf flowering are also possible explanations that this single-year study cannot disentangle.

The dissolved organic carbon carried in throughfall also differed by forest type. Specific ultraviolet absorbance at 254 nanometres, a proxy for aromatic and recalcitrant carbon, was highest in spruce stands, whose needles release lignin derivatives and tannins. The humification index was significantly higher in oak throughfall, reflecting more decomposed, humic organic matter. Most revealing was the fluorescence index, which distinguishes microbial from plant-derived organic matter: beech and oak samples had significantly higher values, with medians near 1.9, than pine and spruce samples, which sat near 1.7. Values above 1.9 typically indicate microbially processed carbon, and the elevated readings under broadleaves suggest microbes play a larger role in transforming pollen-derived carbon in those forests — hinting that pollen inputs feed not just trees but entire soil microbial food webs.

For the authors, the implications reach well beyond academic curiosity. Routine throughfall monitoring has historically ignored pollen as a variable, meaning that chemical enrichment previously attributed solely to canopy leaching or atmospheric deposition may in fact be partly pollenic. As climate change pushes flowering earlier and increases airborne pollen amounts across arboreal taxa, these hidden inputs could grow. Masting behaviour in beech and oak — the episodic, synchronized production of enormous seed and pollen crops — introduces strong year-to-year variability that any nutrient budget must now reckon with.

The researchers acknowledge the limitations of a one-year, correlative dataset and call for multi-year studies incorporating canopy architecture, stand age, phenology and insect infestations, as well as stable isotope tracing or controlled exclusion experiments to nail down mechanisms. Still, the message is clear: pollen is not just about reproduction, or even allergies. It is a seasonal fertiliser delivered from the sky, and forests have been banking on it all along. Incorporating pollen surveys into long-term forest observation networks, the team argues, will be essential for accurate nutrient budgets in a changing climate.

Fridges are piling up in laybys across the country as recycling centres refuse to take anymore. It's the backfiring result, in part, of pettifogging green waste disposal regulation, says Ben Pile.

The post Green Rules Mean Britain Can’t Even Recycle a Fridge appeared first on The Daily Sceptic.

In a development that could reshape how chemists recycle one of the most persistent classes of synthetic molecules ever made, researchers have reported a new catalytic strategy that strips fluorine atoms from perfluoroalkyl chains in a controlled, sequential fashion while installing a single boron group at the chain’s terminus. The work, published in Nature Communications, introduces what the authors call zipper polydefluorination-monoborylation, a transformation that walks down a perfluoroalkyl skeleton and removes multiple fluorine atoms in a stepwise cascade before capping the partially defluorinated product with a boron substituent. The achievement addresses a longstanding challenge in fluorine chemistry: while carbon-fluorine bonds are prized in materials and pharmaceuticals for their extraordinary stability, that same stability makes them notoriously difficult to break selectively, leaving chemists with few tools for converting perfluorinated waste streams into useful building blocks.

Perfluoroalkyl substances, often grouped under the umbrella of PFAS chemistry, owe their remarkable properties to the strength of the carbon-fluorine bond, which at roughly 485 kilojoules per mole in fully fluorinated chains ranks among the strongest single bonds that carbon forms. This bond strength, combined with the sheer electronegativity of fluorine, means that perfluoroalkyl groups resist oxidation, hydrolysis, and thermal degradation under nearly all conventional conditions. As a consequence, perfluorinated chains accumulate in the environment and resist standard degradation pathways, prompting intensive research into defluorination methods ranging from photocatalytic single-electron transfer to reductive hydrodefluorination with metal hydrides. Yet most existing approaches suffer from a common limitation: they either remove fluorine indiscriminately, collapsing the entire chain to a mixture of products, or they remove only a single fluorine atom, offering little control over the degree of defluorination. The new study demonstrates a way to achieve the best of both worlds, delivering multi-fluorine removal in a predictable pattern while simultaneously introducing a versatile functional handle.

The conceptual heart of the method lies in what the authors describe as a zipper mechanism. Rather than removing fluorine atoms at random positions along the chain, the reaction initiates at a defined site and then propagates along the perfluoroalkyl backbone one carbon at a time, much as a zipper opens tooth by tooth. At each step along the chain, a fluorine atom is expelled and replaced in sequence, with the reaction front advancing until a thermodynamic or kinetic stopping point is reached. The monoborylation component of the process ensures that once the zipper has run its course, the resulting olefinic or anionic intermediate is intercepted by a boron reagent, furnishing a product in which the boron group occupies a predictable position derived from the original perfluoroalkyl terminus. Organoboron compounds are among the most valuable intermediates in modern synthetic chemistry, serving as partners in Suzuki-Miyaura cross-coupling and as precursors to alcohols, amines, and halides, so their installation at a defluorination site effectively converts a chemical dead end into a synthetic launching pad.

Mechanistically, the transformation draws on the characteristic reactivity of organoboron reagents toward geminal difluoroalkenes, the partially defluorinated intermediates that arise when consecutive fluorine atoms are eliminated from a perfluoroalkyl chain. Perfluoroalkyl chains, when subjected to strong bases or reductive conditions, can undergo sequential beta-fluoride elimination events, each generating a more highly unsaturated species. The boron reagent in the reported system engages these unsaturated intermediates through addition pathways that install boron at the terminal carbon while generating a carbanionic center adjacent to the remaining difluoromethylene unit. That newly formed carbanion is perfectly positioned to expel another fluoride ion, regenerating an unsaturated handle one carbon further down the chain and setting up the next iteration of the cycle. This intimate coupling of borylation and defluorination is what gives the reaction its chain-walking character: each borylation event creates the conditions for the next defluorination event, and the process ripples along the chain until the fluorine reservoir is exhausted or the reagents are consumed.

The practical significance of the work becomes apparent when one considers the fate of the fluorine atoms themselves. In the zipper process, fluorine is released as fluoride ion, which under the reaction conditions is sequestered by silicon-containing trapping agents to form robust silicon-fluorine bonds. Fluorosilicates of this kind are stable, isolable, and, importantly, compatible with industrial processes for recycling fluorine back into hydrofluoric acid, the feedstock from which essentially all synthetic organofluorine compounds are made. In this sense, the method does more than transform perfluoroalkyl chains into borylated products; it also lays the groundwork for closing the fluorine cycle, recovering the fluorine content of persistent molecules in a form that can be fed back into the chemical economy. With global concern over PFAS contamination intensifying and regulatory pressure on fluorinated chemicals mounting, technologies that enable fluorine recovery rather than dilution into the environment carry considerable weight.

From a synthetic chemistry standpoint, the products of the reaction open multiple downstream avenues. Because the boron substituent is installed at a defined position on a partially fluorinated alkyl or alkenyl framework, the resulting molecules retain a programmable mixture of carbon-fluorine bonds and carbon-boron functionality. The remaining fluorine atoms can tune the lipophilicity, metabolic stability, and dipole moment of the scaffold, properties that are actively exploited in medicinal chemistry when designing fluorinated drug candidates. Meanwhile, the boron group serves as a convertible handle, allowing the defluorinated carbon center to be joined to aromatic rings through cross-coupling, oxidized to alcohols, or aminated in homologation reactions. In effect, the method converts a chemically inert perfluoroalkyl group, useful mainly as a passive coating or tail, into a functionalized partial-fluoro skeleton that can participate in the full toolkit of carbon-carbon and carbon-heteroatom bond formation.

The reported study also sheds light on the factors governing how far the zipper travels along a given chain. Chain length, the nature of the substituent anchoring the perfluoroalkyl group, and the stoichiometry of the base and boron reagent all influence the number of fluorine atoms removed and the distribution of products obtained. Through systematic variation of these parameters and careful analysis of the reaction mixtures by nuclear magnetic resonance spectroscopy and mass spectrometry, the authors map out the scope of the transformation across a range of perfluoroalkyl substrates, from short perfluoroethyl groups to longer chains approaching those found in commercial fluorosurfactants. Control experiments interrogating individual elementary steps support the proposed sequential elimination-addition mechanism and rule out alternative pathways involving radical fragmentation or random beta-scission, underscoring the unusually high degree of positional control the method achieves.

Beyond its immediate synthetic utility, the work contributes to a growing body of research aimed at taming the carbon-fluorine bond through the strategy of defluorinative functionalization. Over the past decade, chemists have developed an impressive repertoire of reactions that replace fluorine in perfluoroalkyl and fluoroarene substrates with groups ranging from hydrogen to sulfur, nitrogen, and carbon substituents. What distinguishes the zipper approach is its multiplicity and its directionality: instead of a single substitution event at a single site, the reaction performs many substitutions in a choreographed sequence along a chain, effectively treating the perfluoroalkyl group as a one-dimensional lattice to be patterned at will. This conceptual reframing, from defluorination as bond-breaking to defluorination as programmable editing, may inspire analogous strategies for other polyfluorinated motifs, including perfluoroarenes and perfluoropolyethers, two additional classes of highly persistent fluorinated materials.

Challenges remain before such chemistry can move from the laboratory bench to environmental remediation at scale. The reaction conditions reported rely on strong bases and moisture-sensitive boron reagents handled under inert atmosphere, and the substrates studied are discrete, soluble perfluoroalkyl compounds rather than the polymeric or adsorbed PFAS species that dominate environmental contamination. Scaling the chemistry will require sourcing boron reagents economically, managing the large quantities of fluoride generated, and integrating the transformation with upstream methods for extracting perfluoroalkyl pollutants from water and soil. Nevertheless, the demonstration that a perfluoroalkyl chain can be unzipped in a controlled manner, with fluorine captured in recyclable form and a valuable boron handle installed, establishes a credible chemical pathway toward defluorination that is both productive and selective, a combination that has eluded the field for decades.

As policymakers and scientists grapple with the legacy of fluorine chemistry, work of this kind illustrates a middle path between the wholesale abandonment of fluorinated molecules and their indefinite persistence in the biosphere. The fluorine atom confers properties that industry and medicine continue to depend upon, and the ability to disassemble fluorinated architectures on demand, recovering both the carbon skeleton as a functionalized building block and the fluorine content as a recyclable salt, points toward a more circular future for organofluorine chemistry. The zipper polydefluorination-monoborylation strategy reported in Nature Communications is an early but striking example of that vision made concrete at the molecular level, and it is likely to prompt rapid efforts to extend the concept across the breadth of persistent fluorinated chemicals.

Whether you’re commuting, training or riding for fun, we asked specialists to break down what to know before you buy – from specs and safety to price

• The best bike locks for every budget

For me, cycling is therapy. It’s calming, meditative and uncomplicated. But there’s a catch. To experience the simple joy of riding a bike, you first have to navigate the maddeningly complex process of buying one.

Make no mistake: this is not a straightforward case of marching into Halfords, saying, “One bike, please!” and leaving with a shiny new steed. But, while complicated, it needn’t be stressful.

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© Photograph: Paddy Maddison

© Photograph: Paddy Maddison

© Photograph: Paddy Maddison

Barcode readers excel at quickly identifying groceries and other products. Could a similar idea work at industrial recycling

Apple has increased its estimated trade-in values for most current iPhone, iPad, Mac, and Apple Watch models in the United States. The adjustments give customers slightly more credit toward a new device, although some older Apple hardware and several Android phones have moved in the opposite direction.

The updated values are maximum estimates rather than guaranteed payments. Apple calculates the final credit after confirming the model and inspecting its condition. A damaged display, enclosure problems, missing functionality, or an inaccurate description can reduce the amount offered.

Most of the increases are modest, but they arrive across several of Apple’s largest product categories at the same time. Recent iPhones receive between $10 and $25 more, every iPad category listed in Apple’s summary gains value, and several popular Macs receive larger increases.

The revisions also reinforce the role of trade-ins within Apple’s retail operation. Credit can reduce the cost of a regular purchase, be delivered through an Apple Gift Card, or lower payments at the beginning of an eligible Apple Upgrade lease.

Trade-In Values Rise Across iPhone and iPad

Every iPhone 16 model included in the update receives a higher maximum estimate. The iPhone 16 Pro Max moves from $685 to $695, retaining the highest listed value among the affected iPhones.

The iPhone 16 Pro increases from $550 to $560, while the iPhone 16 Plus moves from $455 to $465. The standard iPhone 16 receives the largest increase within the family, rising by $25 from $435 to $460.

These changes narrow the difference between the standard iPhone 16 and the larger Plus model. The Pro models retain substantially higher estimates, reflecting their higher original prices and stronger position in the used-device market.

An additional $10 or $25 will not transform the cost of an upgrade, but it can offset part of a case, charger, AppleCare plan, or storage upgrade. The difference also becomes more relevant for customers comparing Apple’s direct program with a third-party reseller offering a similar amount.

Apple’s iPad adjustments are more consistent. The maximum estimate for an iPad Pro rises from $670 to $690, an increase of $20. The iPad Air moves from $445 to $460, while the standard iPad rises from $220 to $235.

The iPad mini also gains $15, moving from a maximum of $250 to $265. That means every current iPad category displayed in Apple’s trade-in summary receives a higher estimate.

Apple’s direct trade-in values are generally lower than the prices an owner might obtain through a private sale. The program instead emphasizes convenience: the device can be returned at an Apple Store or sent using Apple’s online process, with the credit connected directly to a new purchase.

A private sale can produce a better return, especially for a recent device in excellent condition. It also requires the owner to set a price, find a buyer, manage payment, and handle the transfer independently. Apple’s program trades some resale value for a simpler exchange.

Mac and Apple Watch Changes Are Less Consistent

Mac trade-in values receive some of the largest increases, but the category also includes notable reductions.

The MacBook Air rises from a maximum of $485 to $520, adding $35. The Mac mini receives the same increase, moving from $340 to $375. The MacBook Pro changes only slightly, increasing from $685 to $690.

Apple leaves the current iMac estimate unchanged at $355. The Mac Studio receives a larger increase from $975 to $1,045, reflecting the higher value retained by recent desktop configurations.

Older professional desktops move in the other direction. The iMac Pro falls from $325 to $315, while the top Mac Pro estimate declines from $2,090 to $2,045.

That $45 reduction at the top of the Mac range means Apple’s maximum Mac trade-in offer decreases even though several mainstream models receive more credit. The changes appear more closely connected to the resale position of individual product families than to a uniform increase across every computer.

Mac estimates can vary considerably because one model name can cover different years, processors, memory configurations, storage capacities, and physical designs. Apple asks for a serial number before producing a more specific estimate for a Mac.

The Apple Watch adjustments are similarly mixed. Apple Watch Ultra 2 rises from $295 to $305, while Apple Watch Series 9 increases from $120 to $130.

Apple Watch Series 10 remains unchanged at a maximum of $150. The original Apple Watch Ultra falls from $215 to $205, losing $10.

Wearable trade-in values can decline quickly because watches receive frequent updates and are exposed to greater physical wear than many computers or tablets. Battery condition, display damage, case wear, and working buttons can influence whether the device receives the estimated credit.

Apple also accepts devices that no longer qualify for monetary value. Those products can be returned for recycling, including older hardware and accessories that would otherwise remain unused.

Android Offers Face Several Reductions

Apple accepts selected smartphones from Samsung, Google, and other manufacturers when customers move to an iPhone. The latest revisions are less favorable to several Android devices.

The maximum Android estimate across Apple’s displayed range decreases from $370 to $360. Individual changes vary by model.

The Samsung Galaxy S23 Ultra drops from $230 to $200, a $30 reduction. Google’s Pixel 8 Pro declines from $170 to $165.

Other devices remain unchanged. The standard Galaxy S23 continues to carry an estimated value of up to $125, while the OnePlus 12 remains at up to $200.

Apple’s Android offers are primarily designed to remove friction for people moving to the iPhone. They do not necessarily match the amount available from the manufacturer, a carrier promotion, or a private buyer.

Carrier promotions can advertise considerably higher trade-in credits than Apple, particularly around a new iPhone launch. Those offers commonly require an eligible unlimited plan, a new line, monthly bill credits, or a commitment lasting two or three years.

Apple’s direct credit is easier to understand because it is tied to the assessed value of the device rather than a long carrier agreement. The best choice depends on whether the customer values flexibility, immediate credit, or the largest possible promotional discount.

A Higher Estimate Is Not the Final Offer

Apple’s published figures represent the maximum available for qualifying devices in suitable condition. The online estimate is based on the answers supplied before the product is inspected.

After receiving the device, Apple or its trade-in partner verifies its identity and checks whether it powers on, functions properly, and matches the reported condition. A difference can produce a revised offer.

Customers can accept or reject a lower revised value. Rejecting it cancels the trade-in and returns the device, although the payment arrangement for the accompanying purchase may also be adjusted. If the inspected value is higher than the original estimate, Apple says it automatically increases the credit.

The way the credit is delivered depends on the purchase. When a customer pays in full for a new iPhone, iPad, Mac, or Apple Watch, the confirmed value can be returned to the original payment method up to the price of the new product. Any remaining amount can be issued through an Apple Gift Card.

With an eligible monthly payment arrangement, the estimated credit can be applied directly to the new device’s purchase price. Under Apple Upgrade, a qualifying trade-in owned by the customer can reduce payments across the initial lease term. Another device cannot be traded in each time the customer exercises the lease’s upgrade option.

Values also differ between countries and can change without a product announcement. The revised dollar amounts apply to Apple’s United States program, while local market prices, available models, currencies, and trade-in partners determine estimates elsewhere.

Anyone considering an exchange should obtain a fresh estimate shortly before purchasing. Apple requires the trade-in device to arrive within the specified return period and says an online estimate is generally protected for 14 days after the customer receives the new product.

The post Apple Raises Trade-In Values for Most iPhone, iPad, Mac, & Watch Models appeared first on AppleMagazine.

After a closet cleanout, what options are there for recyling our old threads? Not many. Apart from bringing

While recycling is a mathematically obvious response to the finite, non-renewable nature of many resources, the economic math is often challenging. For many materials, it can be hard to compete with virgin materials on a cost basis. Fast-moving technologies like electric vehicles throw in an added complication: By the time a car is scrapped, the industry may have moved on to a different battery chemistry. That reduces the value of recycling the car’s battery back into the production chain.

Still, a study led by Xin Xiong at Nanjing University finds that in China, recycling could become the dominant source of many key materials needed to manufacture EV components over the coming decades.

Modeling manufacturing needs

The researchers set out to model how the supply of recycled materials compares to manufacturing demand in China between 2010 and 2050. It covers materials relevant to batteries across hybrid, battery-electric, and even fuel-cell vehicles (lithium, cobalt, nickel, manganese, phosphorus, sodium, sulfur, and graphite), as well as several critical elements used in electric motors (copper, neodymium, dysprosium, samarium, and cerium).

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While recycling is a mathematically obvious response to the finite, non-renewable nature of many resources, the economic math is often challenging. For many materials, it can be hard to compete with virgin materials on a cost basis. Fast-moving technologies like electric vehicles throw in an added complication: By the time a car is scrapped, the industry may have moved on to a different battery chemistry. That reduces the value of recycling the car’s battery back into the production chain.

Still, a study led by Xin Xiong at Nanjing University finds that in China, recycling could become the dominant source of many key materials needed to manufacture EV components over the coming decades.

Modeling manufacturing needs

The researchers set out to model how the supply of recycled materials compares to manufacturing demand in China between 2010 and 2050. It covers materials relevant to batteries across hybrid, battery-electric, and even fuel-cell vehicles (lithium, cobalt, nickel, manganese, phosphorus, sodium, sulfur, and graphite), as well as several critical elements used in electric motors (copper, neodymium, dysprosium, samarium, and cerium).

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Researchers redesigned a hard plastic so it can be broken down and rebuilt.

The advance could provide a scalable route to clean energy while making plastic recycling more effective. A discarded bottle, shopping bag or car part can remain in the waste stream long after its useful life ends. Although plastic is everywhere in modern society, recycling it remains difficult because most systems require different types to be [...]

Researchers are turning toxic, centuries-old ammunition into highly efficient and cheap solar panels.

Syntetica, a French startup that has developed a novel approach to recycling nylon, has already obtained big-name partners and investors.

In a groundbreaking decade-long study analyzing São Paulo’s urban landscape, researchers have revealed how the expansion of bike lanes and public parks profoundly influences physical activity and public health. Between 2014 and 2024, the city’s bike lane network surged from 242 to 743 kilometers, complemented by the addition of 15 municipal parks. This urban transformation was linked to increased transport-related cycling, emphasizing the critical role of accessible infrastructure within a 500-meter radius of residents’ homes.

The study’s multidisciplinary approach combined longitudinal surveys of 1,500 residents with geospatial datasets from the Geosampa platform, enabling precise correlation between environmental changes and behavior. Findings indicate that proximity to bike lanes significantly counteracts declining bicycle use trends, suggesting these facilities serve as protective factors promoting sustained physical activity. Such activity reduction directly translates to lower risks of cardiovascular disease, cancer, and improved mental health outcomes like reduced anxiety and depression.

Importantly, the research underscores active transportation infrastructure not only as a logistical planning tool but as a vital public health strategy. By reducing reliance on automobiles, these interventions diminish air pollution and traffic-related accidents, thereby contributing to climate change mitigation efforts. However, the study highlights uneven developments: wealthier neighborhoods received disproportionate infrastructure investments, calling for policy shifts to equip underserved zones with similar amenities.

Beyond infrastructural improvements, the researchers emphasize that sociocultural elements and affordability constraints also limit cycling uptake. Despite increased bike lanes, economic barriers such as the high cost of bicycles and gender disparities in cycling participation suggest that integrated approaches—encompassing recreational street design, bike-sharing expansions, and commuter support facilities—are necessary for meaningful behavioral shifts.

An illustrative testimony comes from a local photographer who transitioned from motorbike to bicycle commuting due to new bike bridges providing direct, safer routes. While embracing cycling’s growth, he voices concerns about road space allocation favoring cars and the emerging challenges of cyclists’ vulnerability amid the rise of faster electric bikes. Additionally, issues of public safety and bike theft remain barriers to broader adoption.

Overall, the findings reveal that São Paulo’s urban planning efforts over the past decade represent a promising model of how thoughtfully designed public open spaces can foster healthier, more sustainable cities. Still, ensuring equitable access and addressing multifaceted cultural and socioeconomic factors remain essential for realizing the full potential of active transport systems.

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Subject of Research: Public open spaces and transport-related cycling in urban environments
Article Title: A decade-long study on public open spaces and transport-related cycling in the largest Brazilian city
News Publication Date: 13-Apr-2026
Web References: https://dx.doi.org/10.1016/j.jth.2026.102323
Image Credits: Phelipe Janning/Agência FAPESP

Keywords

Urban planning, Transportation, Public health, Cycling, Active transportation, São Paulo, Infrastructure, Mental health

In an unprecedented exploration of Earth’s dynamic geological processes, researchers have delved deep into the sedimentary history of China, unraveling the intertwined influences of natural climate fluctuations and human activities on sediment transfer since the Last Glacial Maximum. This expansive study, published in Communications Earth & Environment, ushers in a new era of understanding about how sediment movement across this vast and ecologically diverse landmass has evolved over tens of thousands of years, with profound implications for environmental science, climate change, and land management strategies worldwide.

Sediment transfer—the movement of soil, rock, and organic material across landscapes by rivers, wind, and human activity—is a critical process governing terrestrial and aquatic ecosystems. It affects soil fertility, landscape morphology, water quality, and carbon cycling, thereby linking the geosphere, biosphere, and atmosphere. Until now, however, the relative roles of climate versus anthropogenic disturbances in shaping sediment dynamics over millennial timescales remained unclear, particularly in regions like China, where dramatic climatic shifts and massive population expansions have coexisted.

The research team, led by Li M., Huang H., and Izumi K., embarked on a multidisciplinary journey combining sediment core analyses, isotope geochemistry, paleoclimatic reconstructions, and historical land-use records. Their approach integrated high-resolution dating techniques and advanced computational modeling to discriminate between sediment deposition patterns driven by natural glacial-interglacial cycles and those triggered by human interventions such as agriculture, deforestation, and urbanization.

One of the cornerstone revelations from this study centers on the prominent sediment flux variations linked to the Last Glacial Maximum approximately 21,000 years ago. During this period, extensive glaciation and colder, drier conditions significantly altered river regimes and erosion dynamics. The researchers documented pronounced reductions in sediment supply due to diminished vegetation cover and altered precipitation patterns, highlighting the impact of climatic extremes on Earth surface processes.

Moving forward into the Holocene epoch, the warming climate catalyzed vegetation recovery and increased precipitation, resulting in intensified sediment mobilization. Yet, what sets China apart is the overlay of accelerating human activity from the Neolithic period onward. The study meticulously characterizes how early agricultural expansion began reshaping erosion rates and sediment exports, effectively modulating the natural sedimentary balance established by climate alone.

The team’s integration of paleoenvironmental datasets with archaeological evidence allowed them to trace how intensive land use, particularly during the last 5,000 years, drove landscape erosion that amplified sediment transfer into river basins and eventually into marine sediments. This co-evolution of human societies and sediment dynamics speaks volumes about the Anthropocene’s footprint extending much deeper into antiquity than previously assumed.

Perhaps most strikingly, the researchers observed that over the past two millennia, rapid urban growth, industrial development, and large-scale engineering projects such as dam construction have profoundly altered sediment pathways. The modification of river networks and sediment trapping in reservoirs markedly reduced sediment load downstream, disrupting natural sediment replenishment processes essential for delta stability and ecosystem health.

Equally significant was the finding that climate variability continued to exert influence, occasionally exacerbating or mitigating human-driven sediment trends. For instance, severe droughts and flooding events integrally tied to climate oscillations periodically accelerated soil erosion or sediment deposition, showcasing a complex feedback loop between climate systems and anthropogenic pressures.

From a methodological standpoint, the study demonstrates the power of coupling sedimentological evidence with emerging geospatial technologies and modeling frameworks. The team’s innovative analytical pipeline enabled unprecedented spatial and temporal resolution, paving the way for predictive assessments of sediment flux responses under future climate and development scenarios.

This comprehensive chronicle of sediment transfer across China also underscores broader global concerns. Given China’s pivotal role in regional and global biogeochemical cycles, understanding its sediment dynamics is vital for anticipating downstream impacts—ranging from river delta subsidence and coastal erosion to nutrient loading that affects marine ecosystems far beyond national borders.

Importantly, this work highlights sediment transport as an essential climate indicator and environmental parameter, providing valuable insights into past Earth system behavior. Such knowledge empowers policymakers to devise sustainable land and water management policies that balance developmental goals with ecosystem preservation.

The implications for global sediment budgets are profound, as similar interactions between climate variation and human land use are occurring worldwide. As countries grapple with increasing pressures on landscapes due to population growth and climate change, the lessons from China’s sedimentary history resonate widely, emphasizing the necessity of integrated environmental monitoring and adaptive land management.

By revealing the subtle dance between climate forces and human footprints over millennia, this research reshapes our perception of Earth surface processes as deeply interconnected socio-natural phenomena. It urges the scientific community to look beyond simplistic cause-effect paradigms and embrace complexity when addressing environmental challenges.

In essence, the study represents a paradigm shift in sedimentology and environmental science, illustrating how ancient and modern drivers converge to craft the landscapes we inhabit today. The elegant synthesis of data and theory presented by Li, Huang, Izumi, and colleagues sets a gold standard for future inquiries into Earth’s dynamic sedimentary record.

As the climate crisis advances and human transformations accelerate, understanding these profound historical sediment transfer mechanisms from China offers a crucial blueprint for safeguarding ecological and societal resilience across the Anthropocene epoch.

Subject of Research: Anthropogenic and climatic influences on sediment transfer dynamics across China since the Last Glacial Maximum

Article Title: Anthropogenic and climatic controls on sediment transfer across China since the Last Glacial Maximum

Article References:
Li, M., Huang, H., Izumi, K. et al. Anthropogenic and climatic controls on sediment transfer across China since the Last Glacial Maximum. Commun Earth Environ (2026). https://doi.org/10.1038/s43247-026-03767-7

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Uma experiência mostra que os smartphones velhos e usados podem tornar-se uma solução barata e sustentável para tarefas de computação, sendo capazes de rivalizar com centros de dados.

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A groundbreaking new study has unveiled compelling evidence of enhanced marine burial of terrestrial organic carbon during one of Earth’s most dramatic climate events: the Palaeocene–Eocene Thermal Maximum (PETM). Spanning roughly 55 million years ago, the PETM represents a window into rapid global warming, often considered a natural analogue to modern anthropogenic climate change. This research harnesses innovative biomarker proxies paired with sophisticated mixing models and climate simulations to unravel the complex pathways of carbon cycling between land and ocean during this pivotal interval.

At the heart of this investigation lie branched glycerol dialkyl glycerol tetraethers (brGDGTs) and long-chain n-alkanes, molecular fossils derived from bacterial and terrestrial plant sources, respectively. These biomarkers serve as unique fingerprints that allow scientists to distinguish inputs of organic carbon originating from soils and vascular plants, versus that synthesized or deposited within marine systems. By compiling and analyzing brGDGT and n-alkane data from multiple PETM-aged sediment cores spread across geographically diverse sites—from the High Arctic to the Tasman Sea—the researchers bridged geographic and depositional contexts to create a comprehensive view of carbon sourcing.

The methodology builds on carefully extracted lipid fractions separated via microwave-assisted and accelerated solvent extractions, followed by advanced chromatographic and mass spectrometric techniques. Gas chromatography tandem mass spectrometry (GC-MS/MS) was leveraged for hydrocarbon analyses such as n-alkanes, while high-performance liquid chromatography mass spectrometry (HPLC-MS) targeted polar fractions containing brGDGTs. These high-resolution extraction and detection methods ensured robust molecular quantification critical for downstream proxy calculations.

Several key indices were calculated to differentiate terrestrial versus marine organic carbon sources. The branched-to-isoprenoid tetraether (BIT) index quantitatively captures the balance between soil-derived branched GDGTs and marine archaeal crenarchaeol, with soil endmember values derived from an extensive modern peat and soil database, and marine endmember values from distal ocean sediments. Complementarily, the terrestrial-to-aquatic ratio (TAR), based on the abundance of long-chain versus short-chain n-alkanes, serves as a proxy for vascular plant contributions. These indicators were integrated into a rigorous three-endmember mixing model, facilitating the quantification of soil, plant, and marine fractions in PETM sedimentary organic carbon.

A significant innovation in the study is how the mixing model accounts for conservative tracers insensitive to certain endmembers, enabling refined calculations even when biomarkers partially constrain source inputs. This non-negative least squares approach, solved within a Monte Carlo framework incorporating endmember uncertainty and allowing for minor contributions from uncharacterized sources, generates statistically robust source apportionment. The approach was validated against modern Gulf of Mexico sediments, demonstrating high fidelity in reconstructing known terrestrial versus marine carbon contributions.

Quantifying historical carbon mass accumulation rates (MARs) involved integrating fractionated organic carbon proportions with independently derived sedimentation rates and bulk densities from multiple PETM sedimentary records. Standardizing dry bulk density assumptions based on typical detrital and clay mineral densities ensured consistency across sites. This multi-site MAR assessment revealed nuanced shifts in terrestrial carbon burial efficiency during the PETM, reflecting changes in sediment supply, organic carbon preservation, and coastal-marine interactions under extreme warming conditions.

Climate modeling experiments provided the contextual framework for interpreting these geochemical findings. Utilizing the DeepMIP ensemble within the Paleoclimate Modelling Intercomparison Project (PMIP4) and the Coupled Model Intercomparison Project Phase 6 (CMIP6), simulations were executed with varying atmospheric CO₂ concentrations, ranging from pre-industrial levels to multiples up to sixfold. Normalized mean annual precipitation fields extracted from multi-model means enabled the assessment of hydrologic impacts of elevated greenhouse gas forcing on terrestrial and marine carbon dynamics.

Further nuance is provided by the Hadley Centre’s coupled atmosphere-land model configuration incorporating the MOSES2.1 land surface scheme and TRIFFID dynamic vegetation and carbon cycle model. Spanning two key atmospheric CO₂ scenarios bracketing the PETM transition, this framework allowed estimation of changes in vegetation distribution, soil carbon stocks, and ecosystem productivity under palaeoclimate boundary conditions. These models affirm the plausibility of enhanced terrestrial organic carbon export and subsequent marine burial under PETM warming, as observed in empirical sediment biomarker records.

The sophisticated integration of geochemical proxies, sedimentological data, and model simulations collectively advances our understanding of carbon cycling feedbacks during hyperthermal intervals. Accelerated burial of terrestrial organic carbon in marine sediments would have acted as an important carbon sink mechanism, potentially modulating atmospheric CO₂ levels and climate evolution through the PETM. This insight bridges a critical knowledge gap regarding organic carbon fluxes from continents to oceans during rapid warming events in Earth’s deep past.

Moreover, the study’s methodological framework—combining conservative tracer endmember mixing with uncertainty quantification—represents a transferable approach applicable to other geological intervals characterized by coupled climate-carbon perturbations. It highlights the vital role of molecular-level biomarker analyses in reconstructing paleoecosystem structure and sedimentary carbon sources, deepening our ability to predict carbon cycle sensitivity to future climatic changes.

These findings challenge simplistic interpretations of terrestrial carbon loss during warming, revealing instead that significant portions were transferred and buried in marine environments, emphasizing complex cross-system connectivity. This underlines the importance of integrated biogeochemical and climate modeling perspectives to reconstruct feedbacks governing Earth system resilience and tipping points.

Crucially, the validation of biomarker endmembers via modern analogs—such as the Mississippi–Atchafalaya River system—strengthens confidence in the approach’s accuracy and relevance. By demonstrating model outputs consistent with contemporary river-coastal sediment organic carbon distributions, the study underscores the robustness of proxy-based quantitative source apportionment.

This multidisciplinary effort pushes the frontier in paleoenvironmental science, with implications extending from fundamental deep-time carbon cycle reconstructions to informing projections of future organic carbon dynamics under anthropogenic climate forcing. It exemplifies how state-of-the-art analytical chemistry, sedimentology, and Earth system modeling converge to unravel complex Earth processes critical to understanding planetary climate stability.

Further research building on these results might explore finer temporal resolution biomarker studies, integration with isotopic measurements, and expanded geographic coverage to refine the spatial heterogeneity of organic carbon sources and burial efficiencies. Additionally, investigating mechanisms underpinning organic matter preservation in marine sediments under elevated temperatures could illuminate pathways controlling long-term carbon sequestration.

In conclusion, this seminal work presents unprecedented insights into the enhanced burial of terrestrial organic carbon in marine settings during the PETM, a period typified by rapid, profound climate change. Through an elegant fusion of biomarker geochemistry and climate simulation, it opens new vistas in deciphering Earth’s carbon cycle responses and offers a potent analog to contemporary global warming scenarios.

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Subject of Research: Enhanced marine burial of terrestrial organic carbon during the Palaeocene–Eocene Thermal Maximum

Article Title: Enhanced marine burial of terrestrial organic carbon through the Palaeocene–Eocene Thermal Maximum

Article References:
Inglis, G.N., Hemingway, J.D., Stockey, R.G. et al. Enhanced marine burial of terrestrial organic carbon through the Palaeocene–Eocene Thermal Maximum. Nat. Geosci. (2026). https://doi.org/10.1038/s41561-026-02012-2

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DOI: https://doi.org/10.1038/s41561-026-02012-2

Humanity has littered the sky with the refuse of fossil fuel use, releasing enough CO₂ to change the planet’s climate. We are also chucking incredible sums of carbon in the form of plastics into landfills and into the environment around (and inside of) us. What if cleaning up one of these problems could also help clean up the other?

A new study led by Ruth Ebenbauer at Aarhus University experiments with this idea by upcycling discarded polystyrene into (part of) a material commonly used in carbon-capture systems.

Adding amines

This material is based on amines—a simple chemical group that conveniently acts like a sponge for CO₂. An amine will grab CO₂ molecules when exposed to them, but let go of the CO₂ when heated or depressurized, leaving it ready to go again. The first “CO₂ scrubbers” tried in smokestacks used amines dissolved in water to do this, but solid amines are used in all kinds of carbon-capture systems now because they require less energy. These solid materials—often made into granules similar to the activated carbon in a water filter—have high surface area and high porosity, so the amines can efficiently partner up with CO₂ molecules.

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Thousands of electric vehicles in Waymo’s autonomous robotaxi fleet may eventually give up their used batteries for a very different purpose—contributing up to hundreds of megawatt-hours of stationary energy storage to local power grids.

That prospect comes from a “strategic supply agreement” announced by Waymo and B2U Storage Solutions on June 4. B2U has been repurposing thousands of used batteries from various electric vehicles by installing them in large stationary energy storage projects. Such energy storage facilities can capture excess renewable energy during low demand periods and release such energy when local power grids are experiencing peak demand periods.

“Our business is getting the full residual value out of electric vehicle batteries after they're no longer suitable for automotive use,” Freeman Hall, CEO of B2U Storage Solution, told Ars. “Waymo puts a lot of miles on EVs and their model is expanding rapidly, and so we're just very pleased and honored to be able to work with them.”

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