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Modulation of d–d orbital hybridization via creating asymmetrical paired iron sites for the oxygen reduction reaction

Energy Environ. Sci., 2026, Advance Article
DOI: 10.1039/D6EE01866A, Paper
Zhijun Li, Hongxue Liu, Yunlu Chen, Siqi Ji, Xue Lu, Wenkai Yang, Yu Wang, J. Hugh Horton, Yu-Jia Tang, Xinlong Tian
A coordination manipulation strategy creates paired Fe sites bonded with P heteroatoms, inducing electron spin-state modulation and electronic delocalization to boost ORR activity and stability in both alkaline and acidic media.
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Localized anion-rich solvation structures in low-concentration electrolytes enabled by non-coordinating chaotropes for deep-cycling zinc metal batteries

Energy Environ. Sci., 2026, Advance Article
DOI: 10.1039/D6EE00197A, Paper
Licheng Miao, Guoqiang Ma, Kaiyue Qiu, Zhiyuan Zhao, Minglu Li, Tongqiang Bi, Kai Yang, Yuanyuan Hu, Yuanyuan Wang, Jing Xu, Lei Ma, Zhaoxi Shen, Ning Zhang
The as-designed localized high-concentration electrolyte by introducing a non-Zn2+-coordinating chaotropic in a non-concentrated aqueous electrolyte endows aqueous Zn batteries with excellent deep-cycling stability.
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