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Researchers have detected molecules containing rings and chains of carbon atoms in the vicinity of a rare pair of quasars. The trends in the distribution of these molecules are unexpected, suggesting that more work is needed to understand the conditions surrounding active supermassive black holes.

Infrared Eyes on Molecules in Space

Across the universe, atoms are combining to form molecules, and our ability to study molecules in distant realms has never been better. JWST is particularly attuned to emissions from molecules engaged in a kind of chemical yoga, stretching their bonds and flexing the angles between their atoms.

JWST’s sensitive infrared eyes have allowed researchers to study the distribution, creation, and destruction of both aromatic (containing one or more rings of carbon atoms in which certain electrons spread out within the ring) and aliphatic (containing chains of carbon atoms) hydrocarbons. These molecules have been spotted in a wide array of environments, and now, astronomers are finding them in more distant and more extreme environments than ever before.

Distant Discovery

SDSS J074922.96+225511.7, or J0749+2255 for short, is a quasar pair seen 3 billion years after the Big Bang. The two feasting supermassive black holes are roughly 12,000 light-years apart, giving researchers a glimpse into the late stages of a galaxy merger and a harsh environment in which to study the survival and destruction of molecules.

Researchers studying J0749+2255 with JWST have previously reported the detection of a 3.3-μm emission feature from aromatic molecules. Now, C. E. Mentzer (University of Missouri), Aigen Li (University of Missouri), and Xuejuan Yang (Xiangtan University) have analyzed JWST spectra of J0749+2255 and found not just widespread aromatic emission at a rest-frame wavelength of 3.3 μm, but also aliphatic emission at 3.4 μm, which they attribute to carbon chains branching off from the aromatic molecules. This likely makes J0749+2255 the most distant galaxy in which both aromatic and aliphatic emission has been detected.

Unexpected Trends

Mentzer, Li, and Yang subdivided the observations into 47 regions and measured the strength of the 3.3- and 3.4-μm features in each region. This analysis found strong aromatic emission nearest the quasars and showed that the fraction of carbon atoms bound up in aliphatic chains is highest close to the quasars.

Both of these findings are unexpected: the harsh radiation environment near the two active black holes is thought to break apart chains of carbon atoms attached to aromatic rings (which should decrease the 3.4-μm emission) and possibly destroy small aromatic molecules (which should decrease the 3.3-μm emission) — yet both of these features are strongest near the quasar cores where the radiation should be most capable of molecular destruction.

The authors speculated that the analysis regions centered on the quasars are large enough that they contain gas that hasn’t been pummeled by the quasars’ intense radiation and outflows, leaving molecules intact and able to produce the observed emission. However, this doesn’t explain the trend of stronger 3.3- and 3.4-μm emission closer to the quasars — necessitating further research into the emitting behavior of aromatic and aliphatic molecules under the extreme conditions of a dual quasar’s neighborhood.

Citation

“Widespread Detection of Aromatic and Aliphatic Emission in the Dual Quasar J0749+2255 at Cosmic Noon,” C. E. Mentzer et al 2026 ApJL 1005 L38. doi:10.3847/2041-8213/ae7e86

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