Chloride-based seawater battery material delivers 10,000x boost in ion conductivity

Scientists have boosted the movement of chloride ions through a solid material by up to 10,000 times, advancing efforts to develop seawater-based batteries for large-scale renewable energy storage.
The international team, involving researchers from Switzerland, Canada, and the United States, modified lanthanum oxychloride by adding small amounts of calcium, magnesium, or strontium. The changes significantly improved chloride-ion conductivity, one of the major barriers preventing chloride-based batteries from becoming practical.
The work could help expand battery options beyond lithium, which currently dominates energy storage technologies but faces growing demand and supply concerns.
Unlike lithium, chloride is abundant and can be sourced from seawater. Researchers believe chloride-ion batteries could one day support grid-scale storage systems that store electricity generated by wind turbines and solar farms.
Building ion highways
One of the biggest challenges with chloride-ion batteries is that chloride ions move slowly through solid materials. Their relatively large size makes it difficult for them to travel through battery electrolytes, reducing energy storage performance.
To address this, the researchers altered the atomic structure of lanthanum oxychloride. The modifications created easier pathways for chloride ions to move through the material.
According to the team, calcium produced the strongest effect, increasing chloride-ion conductivity by as much as 10,000 times compared with the unmodified material.
The researchers used ultrabright X-rays at the Canadian Light Source (CLS) at the University of Saskatchewan to understand how the structural changes improved ion transport.
The analysis showed that the added elements made the crystal structure softer, allowing chloride ions to move more freely through the solid electrolyte.
“We’re not looking to entirely replace lithium-ion batteries, but we need other solutions in the next few decades if we are going to meet this massive need that the world will have for hundreds of terawatt hours that allow for effective use of solar and wind,” said Sarbajit Banerjee, professor at ETH Zürich and head of the Laboratory for Battery Science at Switzerland’s Paul Scherrer Institute.
Beyond lithium storage
The researchers emphasize that the technology remains at an early stage. The study does not demonstrate a complete chloride-ion battery but instead establishes a promising electrolyte platform that could support future battery development.
“We are exploring uncharted territory,” said Jingxiang Cheng, a PhD student involved in the research. “We’re expanding the horizon of the battery field and we’re hoping to use this platform to build more on it, and to explore things that lithium-ion batteries are not super good at.”
The team believes alternative battery chemistries will be necessary as demand for energy storage continues to grow alongside the expansion of renewable power generation.
Banerjee noted that the project aims to establish the foundations for more sustainable battery technologies capable of supporting large-scale energy storage in the future.
The researchers also credited the CLS, particularly its VLS-PGM beamline, for enabling measurements needed to understand the material’s behavior at the atomic level.
The study was published in the journal ACS Applied Energy Materials.



