Na₂Mn₃O₇ is a magnetic material that behaves unusually and therefore can provide insight into how magnetism emerges in complex materials. Magnetic materials contain entities known as spins, which can be thought of as tiny magnets with north and south poles. These spins interact with neighbouring spins, and as a material is cooled, they often align into an ordered pattern that extends across the entire material, known as long-range magnetic order.

However, Na₂Mn₃O₇, which contains magnetic Mn⁴⁺ ions, behaves differently. It has strong magnetic interactions, very little disorder, and a two-dimensional arrangement of magnetic ions. Under these conditions, a material with relatively large spins would normally be expected to develop long-range magnetic order at low temperatures. Surprisingly, no magnetic ordering is observed, even at very low temperatures.

The material also exhibits two distinct magnetic crossovers. Around 110-120 K, the magnetic susceptibility reaches a broad maximum, indicating that strong magnetic correlations are developing. Around 60-70 K, a feature appears in the specific heat, showing that the system is undergoing a further internal reorganisation. The presence of two separate temperature scales suggests that the magnetism develops in two stages.

Using theoretical and computational techniques, the researchers showed that this unusual behaviour originates from the crystal structure of Na₂Mn₃O₇. The crystal structure divides the magnetic lattice into strongly connected hexagonal clusters of six Mn ions. These clusters behave like magnetic ‘molecules’, with the spins inside each hexagon becoming strongly correlated. Interactions between different hexagons are much weaker and frustrated, preventing the formation of long-range magnetic order across the material.

This research is important because it demonstrates that even large-spin magnetic materials can exhibit quantum-disordered behaviour. More broadly, it shows that crystal structure can be used as a tool to engineer new magnetic states by organising spins into strongly correlated clusters that suppress conventional magnetic ordering.

“What is striking in Na₂Mn₃O₇ is that the crystal structure does more than slightly distort the magnetic lattice. It reorganises the spins into strongly correlated hexagons that behave as emergent magnetic molecules, while frustration and quantum fluctuations prevent these units from ordering collectively.“ – Yasir Iqbal, Indian Institute of Technology Madras

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Frustrated magnets in high magnetic fields—selected examples by J Wosnitza, S A Zvyagin and S Zherlitsyn (2016)

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Graphene, an atomically thin material of a single layer of carbon atoms, is a fascinating material for high-speed electronics, spintronic devices, and neuromorphic components due to its exceptional tunable electrical conductivity. One area of research focuses on understanding how electrons flow through graphene to enable the design of advanced devices. For applications, ultrathin metal-oxide layers (e.g., aluminum oxide and titanium oxide) are routinely deposited on graphene, which deliberately alter electron flow and provide greater control over its properties, in devices ranging from transistors to spin valves. However, although the effects of these coatings are known, researchers have not previously been able to directly observe what is happening inside the device. Instead, their understanding has relied primarily on theoretical models, numerical simulations, and indirect electrical measurements.

In this work, the researchers used X-ray Photoelectron Spectroscopy (XPS) to map electrical potentials across devices while they were operating. They examined the electrical landscape, identifying regions with steep slopes corresponding to strong electric fields and flatter regions corresponding to weaker electric fields, to determine how oxide coatings modify this landscape. They found that metal oxides flatten the electrical landscape through a process known as p-type charge-transfer doping. This occurs when the oxide removes some electrons from the graphene, altering its local electrostatic environment and reducing the voltage gradient. As a result, local electric fields become weaker. The oxide layers suppress the electric fields, reducing them by more than 50%, a significant effect for device operation. A key advance of this research is the visualisation of this effect at very high spatial resolution, whereas previously it could only be inferred from electrical resistance measurements. In addition, by making a direct comparison with electrical measurements, the researchers confirmed the observed effects are due solely to electrostatics and charge redistribution.

Modern electronic devices increasingly depend on controlling electricity at very small scales. By locally adjusting electric fields using oxide coatings, researchers gain an additional design tool that enables different regions of a graphene circuit to be tuned independently. This is particularly important for spintronic devices, which are highly sensitive to local electric fields, and neuromorphic computing hardware, which requires precise control of local electrical properties.

This work represents a breakthrough in the ability to directly map charge distributions and electric fields inside operating 2D-material devices, enabling improved device design.

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Phonons and thermal transport in graphene and graphene-based materials byDenis L Nika and Alexander A Balandin (2017)

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