A new phase of solid superionic ice has been created for the first time in the laboratory. By heating a tiny sample of ultrapure water while compressing it to extreme pressures, physicists at the French Alternative Energies and Atomic Energy Commission (CEA) succeeded in forming an ice phase that features a hexagonal close-packed (hcp) structure and liquid-like hydrogen diffusing through a solid lattice of oxygen atoms. This demonstration could help us better understand the structure of ice giant planets such as Uranus and Neptune, which may harbour this form of ice deep within their interiors.

Unlike water’s familiar liquid, vapour and ice phases, superionic ice can only exist when water is subjected to tens or even hundreds of GPa of pressure at temperatures above 1000-2000 K. Under these conditions, theory predicts that hydrogen ions (protons) diffuse so readily through empty sites in water’s oxygen lattice that the material’s ionic conductivity may exceed 100 Siemens per centimetre, making it almost as conductive as metals. The melting temperature of this form of ice is also extremely high, reaching several thousand kelvin as new ice structures develop that feature a close-packed oxygen lattice.

Diamond anvil cells and X-ray diffraction spectra

To create super-high pressures in the laboratory, researchers typically use diamond anvil cells, which are tiny cavities in which samples are tightly compressed between the tips of two opposing diamond surfaces. In the new work, a CEA team led by physicists Alexis Forestier and Gunnar Weck added two high-thermal-conductivity cup-shaped discs made of boron-doped diamond to the diamond anvil surfaces. This set-up enabled them to apply pressure while heating their 12 micron-sized sample uniformly with lasers, thereby avoiding the large temperature gradients that complicate measurements in conventional diamond anvil cells.

Forestier, Weck and colleagues heated their sample of ultrapure water from 300 to 2630 K while applying pressures between 80 and 229 GPa. Thanks to the Extremely Brilliant Source’s sub-micron beam – part of the ID27 beamline at the European Synchrotron Research Facility in Grenoble – they were able to obtain high-quality X-ray diffraction spectra despite the small size of their sample. According to the CEA researchers, these spectra clearly showed a new hexagonal close-packed (hcp) phase of superionic ice emerging alongside a previously observed face-centred cubic (fcc) phase across a pressure range of 130-200 GPa and temperatures above 1800 K.

A link to Uranus and Neptune

The discovery brings the total number of superionic phases of water to three, with the other being the body-centred cubic phase first observed in 2016. But that’s not all. Forestier, Weck and colleagues say that their results, which they report in Physical Review Letters, could also help explain the magnetic fields of Uranus and Neptune.

Unlike the Earth’s magnetic field, these fields are skewed and off-centre with respect to the planets’ axis of rotation. These properties have led scientists to hypothesize that instead of being generated by the motion of molten iron in the planet’s core (as on Earth), the magnetic fields of Uranus and Neptune could arise from conductive superionic warm dense ice (composed of water, ammonia and methane) in the planets’ outer third.

“The experimental observation of this new hcp superionic phase now provides a rationale for incorporating its mechanical properties and ionic conductivity into these models of planetary interiors,” Forestier says. “Indeed, this phase can coexist with the fcc superionic phase and become more stable at higher pressures (above 150–200 GPa), and so probably exist deeper within the inner shell of these ice giants.”

The researchers’ next step will be to precisely define regions of the phase diagram where pressure and temperature are stable; map out the transition lines between the different phases (molecular and superionic); and understand how the new hcp phase behaves as it melts. This will help confirm whether these phases are stable and present within Uranus and Neptune, Forestier tells Physics World.

“We also want to obtain more direct experimental signatures of superionic behaviour, beyond the thermal expansion we observed,” Weck adds. “Brillouin spectroscopy measurements, for example, could reveal anomalies in the speed of sound, strengthening the evidence for proton diffusion.”

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The Moon’s polar regions may be less hostile to microbes than previously thought. This is the new finding from researchers at NASA and the University of Maryland in the US who say that future crewed missions to the lunar south pole will have to be carefully thought out to limit the unintended transfer of Earth life forms.

High ultraviolet radiation and temperatures make the Moon’s surface a harsh place and not somewhere bacteria and other micro-organisms can easily survive. This is particularly true for the equatorial regions, where all previous crewed missions have been sent. Things might be quite different at the lunar poles, however, since sunlight strikes these high-latitude regions at a low angle because of the Moon’s minimal tilt to the Sun of 1.5°. The result is long permanent shadows where it is cooler. The moonscape is also as rugged here as elsewhere with mountains and hills, which also cast shadows, and deep craters protected from the Sun’s heat and ultraviolet flux. These conditions allow for water ice too.

Because of these unique properties, future crewed missions, such as NASA’s Artemis IV, are scheduled to go to the Moon’s south pole, which has also been identified as a possible future location for a human outpost. The polar regions have already been observed by spacecraft such as ESA’s SMART-1, India’s Chandrayaan, Japan’s Kaguya and NASA’s Lunar Reconnaissance Orbiter. These provided a wealth of information that will be used to prepare future missions.

The problem is that no matter how stringent the sterilization procedures are prior to take-off, the astronauts on these missions will take microbes from Earth with them. Indeed, humans carry millions of microbes on their skin and even more in their bodies.

Landing sites for Artemis IV

To investigate whether microbes could survive in the polar regions, the researchers, led by Prabal Saxena, who works at NASA’s Goddard Space Flight Center, and Stefano Bertone at the University of Maryland, modelled how bacteria and fungi commonly found on human skin would behave in the environment of three candidate landing sites for the upcoming Artemis IV mission. The researchers began by making highly resolved spatial maps of the topography in these regions that included ruggedness, slopes and shadowing effects. They also modelled the UV exposure and temperature in these regions to identify specific locations where micro-organisms could survive for at least 24 h.

They obtained seasonal temperature data on length scales of 240 m from measurements by Lunar Reconnaissance Orbiter’s (LRO) Diviner. As for estimated regional UV (≤320 nm) fluxes, these were gleaned from averaged illumination maps with a pixel scale of 60 m based on topography derived from LRO Lunar Orbiter Laser Altimeter (LOLA) measurements.

“Since the temperatures at the lunar poles are rarely high enough to kill bacteria and low temperatures can preserve microbes on Earth, UV radiation is generally likely to be more dangerous in these regions, says Saxena. “We therefore analysed UV fluxes at finer spatial scales using a technique called ray tracing, and for some regions, included optical effects such as reflection and refraction as sunlight hits the Moon’s surface, leveraging updated LOLA-based topography maps on a scale of 5 m/pixel.”

Understanding how sunlight behaves at the poles is crucial, he adds. “Since the Moon has a very small axial tilt, the Sun appears to hover just above the horizon here, so even small hills and rocks can prevent light from reaching lower-lying ground, creating small, shadowed areas protected from UV rays.”

Up to seven days survival

The simulations revealed that the bacteria and fungi studied could survive in certain niches for up to or potentially beyond seven days. One particular fungus, the Aspergillus, is particularly resistant to UV radiation and could potentially survive in 15 to 30% of the areas assessed, even those that receive some sunlight during the lunar winter. The reconstructions also showed that all five microbes in this study, Bacillus, Deinococcus, Staphylococcus, Aspergillus and Fusarium could possibly survive in certain areas of the De Gerlache Rim’s permanently shaded regions, including when scattered UV light is incorporated into the simulations.

Survival does not mean growth (which requires active metabolism and potential reproduction), however, stresses Saxena. Indeed, surviving microbes are in a dormant, so-called cryptobiotic state and would only grow if the conditions were amenable to life – which is not the case for the Moon as we currently understand it.

“Cells may also be dead,” he tells Physics World, “but even dead cells may persist in the environment as another potential source of contamination.”

The work could apply beyond the Moon, he says. Indeed, a number of different airless bodies such as Mercury, Ceres, some asteroids and comets and exoplanets that may have similar properties could also have potential survivable niches for microbial life. Understanding how these niches may exist, how life may be transferred to them and how human exploration may leave its mark will all serve as a key testbed for future potential human exploration of Mars, which likely has far more habitable environments.

“We need to understand what was there before us, because when we search for signs of life beyond our planet on these bodies, we will want to make sure it’s not stuff we brought,” says Saxena.

The research is described in Science Advances.

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