Researchers at the Helmholtz-Zentrum Berlin (HZB) in Germany have overcome a long-standing barrier in next-generation photovoltaics by developing a new type of all-perovskite triple-junction solar cell. Perovskites are a class of synthetic materials with a unique crystal structure that excel at absorbing light, while a triple-junction design stacks three distinct perovskite sub-cells together, each tuned to capture a different part of the solar spectrum to maximize energy harvesting. With this combination, the device achieved a power conversion efficiency of 27.3%.

Stacking three such individual sub-cells allows multi-junction devices to bypass the theoretical efficiency ceiling of traditional single-junction solar cells. However, their real-world implementation has been severely constrained by optical and electrical losses at the buried interfaces of their narrow-band-gap sub-cells. By introducing a novel graphene oxide and self-assembled monolayer (SAM) bilayer strategy, the HZB team has effectively suppressed these losses, unlocking both high efficiency and unprecedented operational stability.

The challenge of buried interfaces

The main bottleneck in multi-junction all-perovskite architectures centres on the narrow-band-gap tin-lead bottom sub-cell, which captures near-infrared light. For years, the field has relied on an organic polymer called PEDOT:PSS as the hole-transport layer to extract positive charges from this sub-cell. However, PEDOT:PSS suffers from a high degree of parasitic light absorption, robbing the underlying bottom cell of valuable incoming photons. Furthermore, its highly acidic and hygroscopic nature chemically degrades the sensitive perovskite material, creating a critical compromise between efficiency and device lifespan.

This results in a severe material trade-off, whereby a layer intended to extract electric charge ends up blocking the very light needed to generate that charge, all while slowly destroying the underlying solar cell structure.

To move away from PEDOT:PSS, researchers have frequently looked to SAMs, molecularly engineered alternatives that perform exceptionally well in pure lead-based perovskites. Yet, when deposited directly onto tin-lead perovskite layers, SAMs present an unexpected physical anomaly, triggering severe internal electrical field screening and inducing uneven grain growth at the buried interface. Using fast-hysteresis measurements and bias-assisted charge extraction measurements, the HZB team discovered that standard carbazole-based SAMs lead to massive ion accumulation, which severely hinders the cell’s ability to separate and extract photogenerated charge carriers.

Unlocking charge flow with a molecular bilayer

Led by Steve Albrecht, the HZB team designed a synergistic bilayer to circumvent this destructive ion accumulation and field-screening mechanism. They deposited an ultrathin, uniform layer of hydrophilic graphene oxide directly onto the transparent indium tin oxide conductive base, before introducing a specialized SAM molecule, MeO-2PACz. The phosphonic acid head groups of the SAM anchor strongly onto the oxygen-containing functional groups of the graphene oxide via hydrogen and covalent bonding.

This chemical arrangement prompts a favourable molecular reorientation that deepens the layer’s electronic work function, markedly enhancing its electrical conductivity. Additionally, the graphene oxide provides a smooth, hydrophilic foundation that accelerates crystal nucleation, generating a uniform, high-quality perovskite film completely free of the microscopic empty spaces (nanovoids) that plague SAM-only devices in this study.

When integrated into single-junction tin-lead solar cells, the new bilayer achieved a standalone power conversion efficiency of 22.1%, heavily outpacing the 12.0% efficiency of SAM-only equivalents. Using optoelectronic characterization, the team confirmed that this massive improvement was driven almost entirely by the mitigation of internal electronic and ionic extraction losses.

Record stability and the path to 30%

The researchers demonstrated the true potential of this technique when they integrated the bilayer into a monolithic triple-junction stack featuring sub-cells with band gaps of 2.00, 1.60 and 1.25 eV. By replacing the conventional gold and PEDOT:PSS interconnecting layers with an optimized indium tin oxide and graphene oxide/SAM bilayer configuration, they minimized parasitic light absorption in the near-infrared spectrum. This structural optimization raised the short-circuit current density of the narrow-band-gap bottom cell to 10.3 mA/cm², driving the overall triple-junction efficiency to 27.3%.

Beyond the efficiency milestone, the chemically benign and robust nature of the graphene oxide/SAM interface yielded exceptional longevity. While traditional PEDOT:PSS-based cells degrade rapidly due to chemical interactions, the encapsulated bilayer devices successfully retained 90% of their initial performance after 770 h of continuous operational tracking under 1-sun illumination at room temperature. This sets a new stability record for triple-junction all-perovskite configurations.

The team notes that the current triple-junction performance is still bound by slight current mismatches and series-resistance transport losses across the interconnecting sub-cell junctions. By further optimizing the quality of the wider-band-gap perovskite layers and fine-tuning the band alignments of the intermediate contacts, the researchers project that the efficiency of this multi-junction solar architecture can comfortably clear the 30% barrier in the near future.

The solar cell design is detailed in Joule.

The post Bilayer approach ramps performance of all-perovskite triple-junction solar cells appeared first on Physics World.

A compound produced in the body after eating pomegranates improved heart function by up to 80% in experimental models of a type of heart failure with limited treatment options. For people with heart failure with preserved ejection fraction, the heart can still pump blood but struggles to relax and refill properly between beats. In experimental [...]

That’s now just 1 billion years for all the apparatus to hit on the lucky combination randomly, unless we start with design principles.

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How immune cells develop and retain memory may work differently than medical scientists previously believed, according to an international team of researchers.

The new work shows that T cells—white blood cells essential to immune function—can respond to the physical properties of their surroundings through a kind of cellular sense of touch.

The researchers published the work in Nature Immunology, altering our understanding of how immune cells develop, and potentially improving scientists’ understanding of how the immune system adapts to the varied physical environments found throughout the human body.

T Cells Explained

The various specialized types of T cells serve crucial roles in the immune system. Some directly fight infections, while others help coordinate the immune response. Scientists have long believed that biochemical signals help shape the memory T cells that persist in tissues following an infection, preserving the body’s ability to respond to previously encountered threats. How these cells migrate and eventually settle into strategic positions throughout the body is a key part of the immune response.

As T cells travel through the body, they continually monitor for signs of pathogens. When a threat is detected, T cells can enter affected tissues and help clear the infection. Once the invaders have been repelled, some T cells remain in the tissue to guard against reinfection. These tissue-resident memory T cells help defend against previously encountered threats but can also play roles in autoimmune disorders and the rejection of transplanted tissue.

Over their lifetimes, T cells can develop into increasingly specialized forms. Naive T cells have not yet encountered the specific antigen they are capable of recognizing. Following activation, they can differentiate into effector T cells that help target a particular threat, with some eventually developing into long-lived memory cells.

Tissues in the Body

Tissues in our bodies vary widely in stiffness, ranging from the very soft adipose tissue that makes up our body fat to the much stiffer skeletal muscle tissue. These differences raise an interesting question: how do T cells remain strong enough to survive the pressures of stiffer tissues while staying soft enough to change shape as they slide through obstacles in our bodies?

For their laboratory experiments, the researchers reproduced typical tissue stiffnesses using specially engineered collagen gels. They then placed human and mouse immune cells into the gels and discovered that T cells were more likely to develop characteristics associated with tissue-resident memory cells in stiffer environments.

Previously, scientists believed biochemical signals were the primary driver of tissue-resident memory T cell development. In their new research, the team found that these cells use touch to sense the mechanical pressure of their surroundings, dictated by tissue stiffness, and adjust their morphology to compensate.

“This is an exciting fundamental finding that challenges the way we think about immune cells,” said lead author Judith Mandl, a professor in McGill University’s Department of Physiology. “It suggests T cells can ‘feel’ their surroundings and adapt to them, making the physical environment an active force in shaping their behaviour.”

Correcting T Cells

While T cells normally function to protect us from illness, they can occasionally create problems of their own. Patients with autoimmune diseases and allergies may see these immune cells begin attacking healthy tissue. Additionally, organ transplant patients typically require immunosuppressant drugs to stop their T cells from rejecting the new organ.

“Tumours are often dense and physically difficult for immune cells to penetrate. Understanding how T cells adapt to these environments could help researchers design cancer immunotherapies that are better able to reach and attack tumours,” said Mandl.

This new research is an important first step in a new understanding of how immune cells differentiate, which could lead to a new foundational understanding of how to correct undesired immune responses.

The paper, “Mechanosensing by T Cells Promotes a Tissue-Resident Memory Transcriptional Program,” appeared in Nature Immunology on July 3, 2026.

Ryan Whalen covers science and technology for The Debrief. He holds an MA in History and a Master of Library and Information Science with a certificate in Data Science. He can be contacted at ryan@thedebrief.org.