Two-dimensional (2D) materials have attracted a lot of attention in recent years for their excellent electronic, thermal and mechanical properties, as well as their interesting quantum effects. While graphene has gathered the most commercial attention, there are hundreds of 2D materials, all of which have different combinations of properties for different applications. A research team headed up at the University of Chicago has discovered some unusual behaviour in the 2D material Fe₅GeTe₂.

Some 2D materials exhibit superconductivity properties and charge orders (in which the electrons are confined in a specific arrangement rather than being able to move freely). Charge orders arise from the reshaping of ground states in the electronic bands of a 2D materials to create flat electronic bands. And these flat bands cause the electrons to move very slowly in the lattice, at speeds much slower than expected.

Extremely flat electronic bands can often become incoherent, due to an ultrastrong electronic interaction strength between charge carriers. In research published in Science Advances, Shuolong Yang and colleagues found that Fe₅GeTe₂ exhibits a charge-ordered state where electrons move both collectively and very slowly, while remaining quantumly coherent.

“I was originally motivated by the fact that Fe₅GeTe₂ was discovered to host multiple structural phases with nearly the same stoichiometry. Each structural phase is associated with its unique electronic and magnetic phase,” says Yang. “These different structural phases have almost degenerate energies, which means that they can all be stabilized at room temperature.”

According to Yang, this discovery prompted two key research questions: What is the nature of each phase? Can we utilize these nearly energy-degenerate phases to encode information?

Fe₅GeTe₂ is part of specific class of 2D materials called van der Waals magnets, which could be used to develop new memory technology. The researchers probed the electronic structure and magnetic states of Fe₅GeTe₂ using angle-resolved photoemission spectroscopy (ARPES). “We were able to surgically probe the electronic band structure of each individual phase region (tens of microns in size) and figure out the physics,” Yang tells Physics World. “This immediately allows us to answer the question of ‘What is the nature of each phase?’”

After discovering that the electronic band was flat in Fe₅GeTe₂, further studies into the material showed that the charge order in Fe₅GeTe₂ was caused by the folding of electronic bands in the Brillouin zone within 30 meV of the Fermi level.

“We revealed a so-called Kondo-like phase, so the localized electronic states strongly interact with itinerant states, resulting in very peculiar, quantum coherent flat bands right at the Fermi level which dictates low-temperature transport,” says Yang. “The discovery of an effective Kondo lattice in a ferromagnetic phase [instead of magnetically non-ordered phase] is quite a surprise from a theoretical point of view, which forced us to go back to the drawing board to understand its physics. We think that that our surprising finding originates from a many-body localized state interacting with the conduction electrons.”

Because of the flat bands, the electronic system wants to spontaneously break the space-translation symmetry. It then forms a new superlattice order commensurate with the original lattice. “Our results provide the first experimental evidence that an interaction-driven flat band can itself drive electronic ordering through flat-band nesting, without relying on Moiré or geometrically frustrated flat-band engineering,” Yang explains. He notes that this “peculiar physics” used to be something obtained in delicately designed, twisted 2D materials. This finding, however, provides a new avenue to study complex many-body physics enabled by flat bands in stoichiometric and strongly correlated materials.

There’s the potential that the material’s different magnetic states could encode information for memory systems. This idea is being trialled by the team by using a micro-focused laser to switch between this observed quantum many-body phase and other phases.

“We’re using carefully designed laser pulses of different frequencies to switch between the multiple phases of Fe₅GeTe₂, including our discovered Kondo-like phase. If successful, we will utilize the many-body physics for some real memory operations,” Yang explains. This follow-on aims to tackle the second stated research question. However, to be practical, it will have to work at room temperature, and these quantum effects have so far only been realised at ultralow temperatures.

“Fundamental work is underway to understand the exact nature of this Kondo-like phase, whether it has any topological properties, and whether it connects to structural defects,” says Yang. “Eventually we want to understand how to microscopically describe such an exotic system.”

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Engineers are constantly striving to improve the safety and performance of electric vehicle (EV) batteries. Much effort has been put into developing new electrode materials over the years, but future improvements may not follow the same path and may just be as simple as utilizing physical pressure.

A recent study, led by researchers at the University of Cambridge, suggests that EV batteries could be made to last up to twice as long, by applying the right amount of pressure to the electrodes. It is, however, a fine balancing act, as too high or too low a pressure can cause the battery to fail. To employ this approach in real world systems, engineers will need to make sure that the process is easily repeatable without significant pressure error, but it’s an interesting avenue of battery engineering that has come to fruition.

“We carried this work out to improve the sustainability of batteries,” says Michael de Volder, one of the lead researchers on the study. “Given that we are not very good at recycling batteries, extending the lifetime of batteries reduces the need for mining critical minerals for making new batteries and therefore improves their sustainability.”

For their study, reported in Nature Energy, the researchers developed a dilatometer with pneumatic bellows to apply pressure to the electrodes. The bellows act like a clamp to maintain a uniform and constant pressure on the electrode, while a sensor detects small volume changes that occur as the battery charges and discharges.

The researchers tested their electrode pressurization approach on commercial nickel manganese cobalt (NMC) lithium-ion pouch batteries (which have a flexible packaging), without changing their electrolyte or electrode composition. By using commercial batteries with a standard setup, they could test them fairly under different pressures.

“In this work we optimized how hard battery anodes and cathodes should be pushed together to maximize the lifetime of batteries,” de Volder tells Physics World. “Importantly, we also unravel which degradation mechanisms kick in if you press too hard, or not hard enough.”

Doubling battery lifetime

The researchers found that increasing the stack pressure fourfold over typical initial values used in conventional coin cells – to an optimal pressure of 12.5 bar – doubled the lifetime of the NMC811 cells. They compared the results with NMC cells tested at an extra-low pressure of 1.5 bar, a low pressure of 3 bar, a medium pressure of 6.5 bar and a high pressure of 37.5 bar.

Different degradation mechanisms emerged at high and low pressures outside of the optimal pressure zone. Low stack pressure accelerated cathode cracking, causing an increase in transition metal dissolution and excessive formation of the solid electrolyte interphase (SEI) layer. The cracking is likely due to a small number of particles bearing most of the mechanical load, leading to localized high-stress concentrations that initiate crack propagation.

Higher stack pressures, meanwhile, caused increased lithium plating on the anode. The team observed that the electrode thickness reduced during initial cycling but then underwent rapid thickness growth. When the electrodes are at their thinnest, they have a lower porosity that limits lithium transport, leading to higher overpotentials and higher lithium plating. This increases the amount of “dead” lithium and reduces the usable lithium inventory in the battery, causing it to degrade faster.

“We found that when the pressure applied to battery cells is sub-optimal, certain dangerous degradation processes can be accelerated. So, in a way, pressure optimization might improve the safety of batteries. However, more research is needed before we can draw reliable conclusions on this front,” says de Volder.

The pressurization results in this study are still in the early stages, but if shown to be viable at scale in commercial systems, could help EV batteries to last longer. In theory, this could give second-hand EVs a higher market value as the vehicle will have a longer battery life when sold. Additionally, if EV batteries can last longer, it will reduce the pressure on lithium mining operations and reduce the amount of raw material required for battery manufacturing (assuming the same demand) – something that is becoming an issue due to the skyrocketing price of lithium.

Cambridge Enterprise, the university’s innovation arm, has filed a patent, so the research team and university obviously see commercial viability in the process. When asked about the team’s future plans, de Volder tells Physics World that “we studied pressure optimization for one specific battery chemistry, but we anticipate that gains can be made in the lifetime of other battery chemistries too”.

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