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Discharge-triggered electronic delocalization via asymmetric motifs suppresses Jahn–Teller distortion in Mn-based layered oxides

Energy Environ. Sci., 2026, Advance Article
DOI: 10.1039/D6EE03005J, Paper
Jiayuan Zhang, Yucheng Fu, Xingyu Lu, Longxiang Liu, Tianwei Cui, Hong Zhu, Yongzhu Fu, Xiang Li
Discharge-induced electronic delocalization via asymmetric Ru–O–Mn motifs actively suppresses Mn3+ formation and Jahn–Teller distortion, achieving near-zero lattice strain and excellent cycling stability for high-energy sodium-ion battery cathodes.
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