The standard explanation for why rain causes corrosion is that water carries dissolved salts and acids to a surface, constant drumming of raindrops abrades whatever protective coating is on it, and oxygen does the rest. Nearly all our tools to prevent this—paints, polymer films, or oxide layers—are built around this idea. But we’ve apparently been missing something important about the rain.

A new study led by Zhongyuan Ni, Rüdiger Berger, and Hans-Jürgen Butt at the Max Planck Institute for Polymer Research in Mainz, Germany, has shown that water drops routinely arrive at a surface carrying an electrical charge large enough to punch through an insulating coating. Not scratch it. Not slowly dissolve it. Electrically blow a hole in it, the way a spark jumps a gap.

Charged rain

The starting point of the study is a phenomenon called "slide electrification," which has only been properly quantified in the past few years. When a water drop slides across an insulating surface like a leaf, a painted wall, a windowpane, or a plastic panel, it strips charge from that surface and leaves an opposing charge behind. The voltages involved are not trivial. Drops charged this way have been measured at up to 9,000 volts.

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Every few years, El Niño or its cool counterpart, La Niña, shifts rainfall across the tropics, dries out Australia, floods parts of Peru, and rearranges the weather on most of the planet. The two are the warm and cold swings of a single system, the El Niño–Southern Oscillation, or ENSO, and that system is the largest source of year-to-year climate variation on Earth. Its swings sit atop the steadily rising temperatures driven by global warming.

But we didn't know whether global warming was making it stronger. It’s possible that the added energy in the atmosphere and oceans was causing its swings to be more dramatic.

“We've been seeing some very strong El Niño events in the late 20th and early 21st century, and what we didn't know was how unusual those are,” said Julie Cole, an environmental scientist at the University of Michigan. Because models disagree with one another and the instrumental data are too short to separate a trend, Cole’s team reconstructed a thousand-year-long ocean surface temperature record by analyzing fossilized Galápagos corals.

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