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Received β€” 31 May 2026 ⏭ RSC - Energy Environment

Beyond electronic effects: hydrogen-bond engineering via N-mediated microenvironment control for accelerated oxygen electroreduction

Energy Environ. Sci., 2026, 19,3551-3563
DOI: 10.1039/D6EE00569A, Paper
Wenhui Jiang, Bingyu Huang, Zhi Cai, Binbing Tang, Dirk LΓΌtzenkirchen-Hecht, Kai Yuan, Yiwang Chen
We constructed cobalt porphyrin frameworks with precise N gradation to unveil the dual role of N: withdrawing electrons from Co sites and forming ordered hydrogen-bond networks to facilitate proton transfer, thereby boosting ORR kinetics.
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