Energy Environ. Sci., 2026, 19,3667-3677
DOI: 10.1039/D6EE00543H, Paper

Yuhang Li, Likun Chen, Shengnan Zhang, Yubin Li, Junwei Liang, Yuetao Ma, Ke Yang, Zhuo Han, Guanyou Xiao, Longxiang Yu, Chenjie Lou, Yan-Bing He, Feiyu Kang, Ming Liu
The TCM⁻ anion prevents the PS₄³⁻ to P₂S₇⁴⁻ phase transition via weak interactions with LPSC. This maintains the PS₄³⁻-based boundaries in HSE-LiTCM, ensuring rapid Li⁺ transport and high conductivity.
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